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| Could someone please explain to me the meaning of the terms "salt" and "mineralization" when describing fertilization? Not having taken college chemistry, I am having a hard time with this. Do only synthetic ferts contain "salts"? Do organic ferts as well? How does the latter mineralize? I am confounded with trying to understand what is happening with fertilizers at the most basic level. regards to all - Minnieoaka |
Follow-Up Postings:
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| I have not fully grasped it either, but am currently taking a mineralization workshop. I have been to class with five more to go. As I understand it, the salts dissolve quickly, so they should only be applied close to planting time or during the growing season. Most everyone has seen that in action when 'epsom salt' (magnesium sulfate) dissolves in water. I believe all the sulfates are salts. So a common way of applying them at garden scale is in solution as foliar spray or soil drench. Distinct from those, it seems, are the 'rock powders', which are supposed to be much less soluble. And yet greensand and langbeinite are said to be fairly quick-acting. Presumably the rock powders have many minerals in them and some of those might be in salt form, I suspect. |
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| Relevant to the question, evaporite mineral rocks. |
Here is a link that might be useful: must be salts
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- Posted by minnieoaka (My Page) on Mon, Jan 31, 11 at 13:41
| thank you for that. Specifically, what is meant when people warn of "salt build up from horse manure" in the case of organic techniques, or salts from 10-10-10 in the case of conventional ferts? Likewise, I've heard that mineralization must occur when making use of organic ferts. Two questions I know but related to same process of getting nutrients to the plant. |
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| I have not been to class, but believe that with a good rain fall or water program you will have little if ant build-up. I have used manures for years with no problems. A soil test for minerals & salt build-up should tell you what you need to do. |
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| A salt is the product of the reaction between an acid and a base. The nutrients plants take up are in salt form. It's not just salt build-up that you need to worry about, it's ANYTHING in the soil that is soluble. Considered only from it's effect on a plants ability to absorb water and the nutrients in water, sugar in the soil solution is just as bad as table salt, because it unnecessarily raises the EC/TDS level in the soil solution, which is what you want to avoid. In the case of manure, there is also the issue of ammonium toxicity to be guarded against. N in organic materials must be "mineralized" to nitrate form or ammonium that is exchangeable before it is in a form that makes it available for uptake. Mineralization occurs during the decomposition of organic materials by microorganisms in soil. Microorganisms feeding on the organic molecules cleave hydrocarbon chains during this decomposition process, freeing elements locked in the chains. Always, the mineralization of N is accompanied by the formation of entirely new organic materials, which might be microbial cells or simply the by-products of the activities of microorganisms. Obviously, the availability of organic materials is the primary factor that determines how much microbial activity/mineralization occurs when soil temperature/moisture/air levels are favorable. Al |
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- Posted by minnieoaka (My Page) on Mon, Jan 31, 11 at 15:46
| I see. Well explained. But please let me ask: are these nitrates and ammoniums considered salts (sorry, I do not know my salts). Also, am I to understand that through mineralization two things occur, 1) N is mineralized into an 'inorganic' form in order to be taken up by plant, and 2) it is accompanied by the formation of entirely new organic materials, as you stated above? |
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| Generally when a chemist talks about salt that chemist is refering to a powder like substance versus a liquid. Although you can also have a salt solution or a powder mixed in a liquid. |
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- Posted by minnieoaka (My Page) on Tue, Feb 1, 11 at 8:03
| Very helpful. All very helpful and it did inspire me to do a little more digging into some basic chemistry, a la my college son's textbook and good old wikipedia. |
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- Posted by gardengal48 PNW zone 8 (My Page) on Tue, Feb 1, 11 at 9:51
| Al's answer is very good but these terms can be confusing as they are used in ways that are different from the obvious or unfamiliar to us unless we are understand exactly how plants take up nutrients or are practicing chemists :-) Plants take up nutrients from the soil only in the form of soluble ions - salts. These are not "salts" as in table salt (although table salt IS a soluble ion) but soluble (dissolvable in water) inorganic chemical compounds that plants take up through their roots and from which the necessary nutrients are extracted during photosynthesis. All synthetic fertilizers are formulated as soluble salts so that, unless treated for extended release, the nutrients are immediately available for uptake by the plants. Salt build-up can, and often does, occur when more fertilizer is applied than the plant can use or take up at that time. In an inground soil situation, many of these salts - because they are soluble - are leached into the surrounding soil and groundwater, leading to pollution. If the soil receives inadequate irrigation, instead of leaching, the salts just accumulate or build up, sometimes leading to dangerous - to the plants - levels. With organic fertilizers, the nutrients are not delivered in a soluble form. They must undergo processing by the soil organisms before they are converted to soluble, inorganic ions/salts that the plants can access. As this is a much slower process with the nutrients in a soluble form being made available over an extended period of time, the risk of salt build-up is much less, as is the potential for leaching. And the nutrient levels of most organic ferts are much lower than those of synthetic ferts, so the risk of over-applying or creating salt build-up and the accompanying 'burning' of plant tissue is much less. 'Mineralization', as it applies to plant nutrients and fertilizers, has nothing to do with minerals! As Al stated, it is part of the nitrogen cycle and describes the process whereby organic nitrogen is converted by the soil microbes into inorganic compounds - the soluble ions - that can be accessed by the plants. |
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- Posted by minnieoaka (My Page) on Tue, Feb 1, 11 at 10:04
| It's so satisfying to get a grip on this.. this is really helpful. So, speaking of terms that get thrown around without much explanation...I've also heard the term 'mineral salts' and that 'mineral salts will build up in the soil'. Am I to conclude that for instance, the salts in a cup of Osmocote can be termed 'mineral salts'? I am trying to nail down TERMS here and get them right. I am getting the process, but as you say, terms are confusing. |
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- Posted by gardengal48 PNW zone 8 (My Page) on Tue, Feb 1, 11 at 11:47
| The term 'mineral salts' is used interchangeably with soluble salts. They are the same thing - inorganic chemical compounds that are taken up by the plants in the form of soluble ions. |
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- Posted by spiced_ham z5 OH (My Page) on Tue, Feb 1, 11 at 22:22
| Mineralization is decomposition of organic material leaving behind inorganic material. In other words, the carbon is removed leaving the "minerals" behind. Example: amino acids (organic compounds with lots of carbon atoms)contain a nitrogen atom and break down to ammonium (NH4)and then nitrate (NO3), with the carbon being released as carbon dioxide CO2. Nitrate (NO3)is an ion. Ionic compounds stick together with ionic bonds which are weak, like sticking two magnets together (+) and (-) charges. Example: calcium nitrate (Ca(+)and NO3(-)) fertilizer salt. Water has "magnetic" charges on each side of the (+)H2O(-) molecule and tends to pull ionic compounds apart so salts usually dissolve in water. Table salt sodium chloride NaCL consists of Sodium Na(+) and Cloride(-) ions which separate in water. Plants take in minerals (ionic compounds) dissolved in water and convert them into organic compounds. Decomposers take those organic compounds and break them back down to the minerals. Not all mineral are ionic compounds, those held together with "tighter" covalent bonds don't pull apart in water. Most "rocks" are covalently bonded minerals. ane exception is limestone [calcium carbonate (CaCO3)] which is a salt with very strong ionic bonds and needs something with a stronger charge than water to pull it apart, generally an acid, which is why soil pH (soil acidity) is important for fertilizer availability to plants. |
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- Posted by vermontkingdom 4a (My Page) on Wed, Feb 2, 11 at 7:40
| That's what is so great about this site. You can get a brief explanation or suggestion about a question or get an extensive informed explanation backed up with solid science facts. It's wonderful we have so many contributors willing to share their considerable expertise. |
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| So in the leachable sandy soils especially salts will dissolve and leach quickly through the soil horizons, correct? Probably to the extent that whatever the crop does not absorb during the growing season would be lost by the next year? Is borax a salt? mangenese sulfate? gypsum? Copper sulfate? |
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- Posted by minnieoaka (My Page) on Wed, Feb 2, 11 at 17:23
| Most grateful to all of you above for the excellent elucidation. |
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- Posted by spiced_ham z5 OH (My Page) on Wed, Feb 2, 11 at 18:51
| Yes, borax, Epsoms salts (mag sulfate), gypsum (calcium sulfate), and copper sulphate are all salts. Each salt is different in its dissociative properties. If you mix epsoms salts (mag sulfate)in with a fertilizer that has calcium nitrate both salts will disolve quickly, but the calcium will then bind tightly to the sulphate so that you are taking both ions out of the system. You often get a white substance buildup on your pots when you do this (same idea with hard water scale =calcium carbonate). The calcium sulphate (gypsum), like limestone (calcium carbonate) will slowly dissociate under normal garden conditions, which is why you only need to add these things to your garden every few years. Clay particles have a charge to them so fertilizer ions stick and stay in the soil longer than with sand. Both bacteria and fungi (microbes) take in fertilizer salts the same way plant roots do. They tend to have a short life span (soil dries out and many die etc) and release the compounds back into the soil for uptake by plants and more microbes in a "recycling" cycle that resists leaching. The microbes need organic material for the carbon they need, so if you have a lot of organic material in your soil it will hold onto minerals longer. This is one misundertanding of alot of organic warriors. It's not the "salt" fertilizers that are bad, it's the low organic content in the soil from intensive agriculture that those fertilizers make possible. Cover crops scavenge minerals from deep (and shallow) soil and release them when they are cut and turned under to rot. Microbes are pretty much stuck to shallower soil depths. |
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| Hope I am not getting off the thread here, but I have believed what you said. The part about salt fertilizers, but the low organic content. When I tell this to other O. Warriors, they reply "that the salts make the microbes anger. This is in a permaculture book, forget the title. Anyway, what say you spiced ham? |
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| Ham, that is just what they have been saying at the seminar I am doing - that many organic operations are starved of minerals because of the disinclination to use the salts. This seminar is by no means conventional ag; I would rather characterize it as beyond organic. I want to be very careful not to use salts in excess quantity, for obvious reasons. Someone in this thread said that salts are not minerals, and yet the various salts do mineralize the soil. One gets mag and sulfur into the system if one introduces mag sulfate to the soil, as an example, so how is that not a mineral? |
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| Before reading this thread, I thought that minerals were specific types of rock, with names like feldspar, magnetite, and mica. I thought that minerals were created in the mantle of the earth, after eons of heat and pressure. And I thought, that, for the most part, minerals were insoluble in water. I understood that minerals were usually complex aggregates of many elements, due the conditions in which they were formed. Salts, on the other hand, are generally soluble in water, and they are the end product when an acid is mixed with a base, after the water is evaporated away. Salts have very specific chemical names, like ammonium sulfate, and they generally are made up of only a few elements. I am not the language police, but I do like to avoid creating confusion when I write, mainly to avoid confusion when I think. I will not be using the term "mineralization" if I can possibly avoid it. There must be better way to describe the breakdown of organic material into soluble ions. |
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- Posted by gardengal48 PNW zone 8 (My Page) on Thu, Feb 3, 11 at 10:16
| I'm sorry if I added to the confusion. Let me be very clear - I never said salts were not minerals. Obviously, in many cases they are. And in fact the terms 'mineral salts' and 'soluble salts' are used pretty much interchangeably. But the term 'mineralization' as it applies to soils and fertilizers only describes a process whereby organic matter is broken down by soil organisms into plant accessible forms. To say that mineralization 'has nothing to do with minerals' exactly was perhaps an oversimplification on my part - these plant accessible nutrients are of course mineral or soluble salts. But this is happening on a molecular level and it is hard to qualify the term 'mineralization' as it is most commonly used and understood with the concept of remineralizing one's soil, as I think some other posters are alluding to. Eric's post above outlines why I said what I did - when most folks think of minerals, they think of rocks. It is confusing to say the least!! From a personal observation, I don't know how you can avoid salts nor should you want to, as that's how the nutrients get delivered. But I think it may be wise to consider how/why you are using the salts, in what volume and most especially, from what source they are being derived. |
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- Posted by minnieoaka (My Page) on Thu, Feb 3, 11 at 11:39
| soil science is vast and according to some experts, "little understood" but as a former english major now switching to horticultural science in my 40's I must say, the clarity of "words" in the field of science is quite poor! Case in point: words like mineral and salt and mineralization. But then again, all language has context and I am having to learn the "context" of of chemistry and soil science |
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| Minnie, once you take some soils science courses, you'll 'get' the specific terminology. And you will appreciate enormously how little is really understood on a day to day basis by the average gardener. Would you mind emailing me? You can find my address in (my page). It's about something off topic and that we share in common. Thanks!
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- Posted by piedmontnc 7b-8 (My Page) on Fri, Feb 4, 11 at 15:37
| I must say, the clarity of "words" in the field of science is quite poor! Case in point: words like mineral and salt and mineralization. But then again, all language has context and I am having to learn the "context" of of chemistry and soil science I find the opposite, it's usually the colloquial terminology vs. the specific scientific terminology where the confusion lies. |
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| Okaaaayyyyy. can we get off the big terminology words & get back to the day to day words. I really like this thread, but who can say the biggest words is not the answer. minnieoaka, a lot of us are learning the context of chemistry & soil science. Some time it is easier to try a test plot/bed to see what will happen. but you have to record what you do, as well as what happens. Much like another thread about how much calcium you can get from egg shells. Thanks for starting this thread, I have confirmed somethings & learn some too. |
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- Posted by spiced_ham z5 OH (My Page) on Fri, Feb 4, 11 at 22:06
| Check out wikipedia for "mineral". The word covers just about everything that isn't an organic compount (carbon + hydrogen + oxygen). The work "Organic" is much looser...if I hear about another actor whose process or role is "organic" my head may pop off. Petrolium are/is an organic compound, but you can't use petrolium/organic pesticides for organic gardening. Synthetic/mineral fertilizers are used in high concentrations to grow mushrooms... so much that undiluted mushroom compost will burn plant seedlings. "potash, urea, ammonium nitrate" http://extension.oregonstate.edu/news/story.php?S_No=28&storyType=gard en You can also add mineral fertilizers to cold compost piles and heat them up again as the microbial populations reproduce. It is especially useful (IMO) for things like big woodchip piles, resulting in a large amount of slow release "organic" fertilizer when the compost is used in the garden. When you turn those piles the inside is full of happy fungi. Sure, you can pour high concentration miracle grow on microbes and it will kill them through osmotic stress (sucks the water out of them like pouring salt on a snail). But that concentration is soon diluted and the doubling time of microbes is in the order of hours (think of mouldy bread) so whatever was killed is soon replaced. Used the wrong way mineral/synthetic/salt fertilizers can pollute the environment from runoff, but that is usually in farming situations or from lawn care practices. You can pollute the water table with organic methods as well. "In one case, alfalfa that was plowed was found to have twice the concentration of nitrates below the root system of the crop compared to fertilized corn." http://extension.missouri.edu/publications/DisplayPub.aspx?P=WQ277
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